Free Access
Issue
J. Chim. Phys.
Volume 95, Number 6, June 1998
Page(s) 1184 - 1187
DOI https://doi.org/10.1051/jcp:1998243
DOI: 10.1051/jcp:1998243


J. Chim. Phys. Vol. 95, N°6  p. 1184-1187

Tetrathiapentalenes: chemical and electrochemical polymerization

H. Müller1, 1 and B. Divisia-Blohorn2

1  European Synchrotron Radiation Facility, BP. 220, 38043 Grenoble cedex 9, France
2  UMR 585 du CEA-CNRS, Université J. Fourier, DRFMC-SI3M-LEM, CEA Grenoble, 17 avenue des Martyrs, 38054 Grenoble cedex 9, France

Abstract
The (electro)chemical polymerization of 1,3,4,6-tetrathiapentalenes 1a (R = phenyl) and 1b (R = thienyl) gave the polymeric compounds 6a and b. The electrical conductivities of these materials amount to $\sigma_{RT}=5~10^{-3} - 5 ~10^{-1}$ S/cm.

Résumé
La polymérisation des 1,3,4,6-tétrathiapentalènes 1a (R = phényle) et 1b (R = thiényle) par voie (électro)chimique a conduit aux polymères 6a et 6b. Les conductivités électriques mesurées de ces matériaux sont $\sigma_{RT}=5~10^{-3} - 5 ~10^{-1}$ S/cm.


Key words: tetrethiapentalene -- conducting polymer -- cyclic voltammetry
Contents

© EDP Sciences 1998

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