J. Chim. Phys.
Volume 63, 1966
|Page(s)||1044 - 1048|
|Published online||28 May 2017|
Vibrational structure of molecular charge transfer bands, part. I. hydrocarbon-tetrahalo p-benzoquinone complexes in solution
Department of Chemistry, University College of Science, Calcutta-9, India.
Under high resolution the electronic charge transfer band of hydrocarbon-tetrahalo p-benzoquinone complexes in chloroform have been found to show vibrational structure of very low frequency of 150-250 cm-1. This has been associated with the change in donor-acceptor bond. The force constant of the intermolecular bond lies in the range
1,35-1,70 X 105 dynes/cm
for a series of complexes.
© Paris : Société de Chimie Physique, 1966