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Cited article:

Metal ion-tetracycline interactions in biological fluids. Part 6. Formation of copper(II) complexes with tetracycline and some of its derivatives and appraisal of their biological significance

Michel Brion, Luc Lambs and Guy Berthon
Inorganica Chimica Acta 123 (2) 61 (1986)
https://doi.org/10.1016/S0020-1693(00)84302-9